1. 个人简介：

2012年6月于安徽师范大学硕士研究生毕业后留校工作，2016年6月取得化学博士学位，2018年8月至2020年7月在香港理工大学应用生物与化学科技系做博士后研究。目前受聘副教授、硕士生导师，主要从事新型有机功能染料的设计开发、性质及其在能源、材料、生物等领域的应用研究。至今，以第一作者或通讯作者身份在Angew. Chem. Int. Ed.、Org. Lett.、Inorg. Chem.?、Chem. Commun.、Mater. Chem. Front.、J. Mater. Chem. C等期刊上发表论文40余篇。论文总被引3000余次。

学术研究兴趣：?多硼氮芳香稠环、聚集诱导发射、双态发射型材料的设计合成、性质及应用

科研工作经历：

2012.7 至 今，安徽师范大学，ut裸聊，硕士生导师

2018.8-2020.7，香港理工大学，应用生物与化学科技系，Postdoctoral Fellow，合作导师：Prof. Wong, Wai-Yeung

? ? ? 学习教育经历：

2013.9–2016.7，安徽师范大学，化学学科专业，博士，导师：焦莉娟 教授

2009.9–2012.6，安徽师范大学，有机化学专业，硕士，导师：焦莉娟 教授

2005.9–2009.7，安徽师范大学，应用化学专业，学士?

2. 主持科研项目：

1) 安徽省自然科学基金面上项目，2408085MB043，新型异吲哚吡啶多硼氮稠环的精准合成及其光电性质，2024.9-2027.12，在研

2) 2023年度安徽省高校科研项目，2023AH050149，高稳定高亮近红外二区双并氟硼二叱咯的设计开发与性质研究，2023.9-2026.8，在研

3) 安徽省博士后研究人员科研活动项目，2021B533，高性能双硼肼桥联水杨酰腙吡咯荧光团的合成、性质及应用研究，2021.11-2023.11，已结题

4) 安徽省自然科学基金青年项目，2008085QB67，新型立体扭曲双硼肼桥联水杨酰腙吡咯荧光团的设计合成、光学性质及自组装研究，2020.7-2022.6，已结题

5) 南京大学配位化学国家重点实验室开放基金，SKLCC1911，近红外二区AIE 型苯并四吡咯配合物的合成、性质及成像研究，2019.2-2021.1，已结题

6) 安徽师范大学博士启动基金，2017XJJ28，肼桥联吡咯类氟硼荧光染料的合成及性能研究，2017.5–2020.5，已结题

7) 国家自然科学基金青年基金项目，21402001，新型α,β位稠环Aza-BODIPY近红外染料的合成及性能研究，2015.1–2017.12，已结题

1) Yu, C.;*?Di, G.; Li, Q.; Guo, X.; Wang, L.; Gong, Q.;* Wei, Y.;* Zhao, Q.; Jiao, L.; Hao, E.* Multicomponent diversity-oriented access to boronic-acid-derived pyrrolide salicyl-hydrazone fluorophores with strong solid-state emission.?Inorg. Chem. 2024, Accepted.

2) Yu, C.;* Sun, Y.; Liu, S.; Li, J.;* Wang, J.; Wei, Y.; Xu, X.;* Yang, M.; Jiao, L.; Hao, E.* Twisted benzothieno-fused BOPHY dyes as triplet photosensitizers with long-lived triplet excited states.?Inorg. Chem. 2024, Accepted.

3) Qian, W.; Wei, S.; Yu, C.;* Sun, Y.; Li, H.; Yu, T.; Zhang, H.;* Li, Y.;* Jiao, L.; Hao, E.* Solid-state emissive meso‐aryl/alkyl‐substituted and heteroatom-mixed BOPPY dyes: syntheses, structures, physicochemical, redox properties and computational analysis. Inorg. Chem. 2024, 63, 5432. DOI: 10.1021/acs.inorgchem.3c04036.? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

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4)孙营柱; 于长江;* 焦莉娟; 徐瑞明; 郝二红;* 李家柱;* 刘鸣华. 苯并噻吩稠合双硼荧光染料的手性光学性质及组装手性放大研究. 《中国科学：化学》, 2024, 54, 1352. DOI: 10.1360/SSC-2024-0016.

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5)?Bu, ?W.; Yu, C.;* Man, ?Y.; Li, J.;* Wu, Q.; Gui, S.;* Wei, Y.;* Jiao, L.; Hao, E.* Heavy-atom-free triplet benzothiophene-fused BODIPY derivatives for lipid droplets-specific biomaging and photodynamic therapy,?Chem. Commun. 2024,?DOI: 10.1039/d4cc02551b.?

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6) Wang, L.; Cheng, C.;?Yu, C.;* Wu, Q.; Kang, Z.; Wang, H.;* Jiao, L.;?Hao, E.*?NIR-absorbing and emitting a,a-nitrogen-bridged BODIPY dimers with strong excitonic coupling, Chem. Commun.?2024,?60, 5054.?DOI:10.1039/d4cc00878b.? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

7) Fu, X.; Man, Y.;?Yu, C.;* Sun, Y.; Hao, E.;* Wu, Q.; Hu, A.; Li, G.; Wang, C.-C.; Li, J. Unsymmetrical benzothieno-fused BODIPYs as efficient NIR heavy-atom-free photosensitizers,?J. Org. Chem. 2024, 89, 4826.?DOI:?10.1021/acs.joc.4c00034.? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ??8) Yu, C.;* Sun, Y.; Jiao, L.; Hao, E.* Recent advances of highly fluorescent hydrazine inserted pyrrole-based bisboron-anchoring fluorophores: Synthesis and properties. Syn. Lett. 2024, ?35, 37.?DOI: 10.1055/a-2045-2369.

9) 宫清宝, 吕翔, 于长江,*?李婉婉, 赵全胜,* 焦莉娟, 郝二红,* 聚集诱导发光活性二氟化硼吡啶肼醛腙的合成、晶体结构及光学性质.?Chin. J. Org. Chem.?2024, DOI: 10.6023/cjoc202403032.

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10) Sun, Y.; Yu, C.;* Qian, W.; Zhang, H.; Jiao, L.; Li, J.;* Liu, M.;* Hao, E.* Dynamically stable co-assembled supramolecular BOPPY systems with chiral amplification.?Chem. Commun. 2023, 59, 13986.?DOI: 10.1039/d3cc04727j.

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11)?Wang, X.; Fu, X.; Bu, W.; Yu, C.;* Hao, E.; Jiao, L.; Wu,* Q.; Wang, R.; Wang, J.; Li, J.*?Bisbenzothieno[b]-fused BODIPYs as efficient near-infrared heavy-atom-free photosensitizers.?Dyes Pigments 2023, 11591.?DOI:?10.1016/j.dyepig.2023.111591.

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12) Yu, C.;* Sun, Y.; Wu, Q.; Shi, Y.; Jiao, L.; Guo, X.; Li J.;* Li, J.;* Hao, E.* Synthesis, properties, and semiconducting characteristics of bisbenzothieno[b]-fused BODIPYs. J. Org. Chem. 2023,?DOI: 1.01021/acs.joc.3c01186.

13) Zhao, X.; Hu, B.; Zhou, Q.; Yu, Y.;?Hao, E.; Guo, X,; Xu, Y.;*?Yu, C.;* Sun, K.;* Lalevée, J.*?Triphenylamine-substituted BODIPY dye based photoinitiators for free radical and cationic photopolymerization under visible LED irradiation and application in 3D printing.?Dyes Pigments 2023, 111880.?DOI:?10.1016/j.dyepig.2023.111880.

14)?Yu, C.;*?Sun, Y.;?Fang, X.; Li, J.;* Wu, Q.; Bu, W.; Guo, X.; Wang, H.; Jiao, L.;?Hao, E.*?Aromatic-ring-fused BOPPY fluorophores: Synthesis, spectral, redox properties, and bioimaging application. Inorg. Chem.?2022, 61, 16718. DOI: 10.1021/acs.inorgchem.2c02517.

15) Yu, C.;*?Fang, X.; Wu, Q.; Chen, N.; Cheng, C.;?Guo, X.; Hao, E.*; Jiao, L.*?Synthesis and spectral properties of aggregation-induced emission-active push-pull chromophores based on isoindole scaffolds.?Org. Lett. 2022, 24, 4557. DOI:?10.1021/acs.orglett.2c01659.?

16)?于长江;*?程超; 郝二红; 焦莉娟.*?芳并氮杂氟硼二吡咯的合成与应用.?《ut裸聊》, 2022, 52, 1371. DOI: 10.1360/SSC-2022-0045.

17) Yu, C.;* Guo, X,; Fang, X.; Chen, Na;?Wu, Q.; Hao, E.; Jiao, L.* Efficiently emissive, strongly slvatochromic and lipid droplet-specific, fluorescent probes for mapping polarity in vitro. Dyes Pigments 2022, 197, 109838. DOI:?10.1016/j.dyepig.2021.109838.

18) Yu, C.;*?Fang, X.; Wang, H.; Guo, X,; Sun, L.; Wu, Q.; Jiao, L.; Hao, E.*?A family of highly fluorescent and membrane-permeable bis(BF2) acyl-pyridinylhydrazine dyes with strong solid-state emission and large Stokes shifts: The BOAPH fluorophores.?J. Org. Chem. 2021, 86, 11492.?http://pubs.acs.org/doi/full/10.1021/acs.joc.1c01042

19) Guo, X.; Tang, B.; Wu, H.; Wu, Q.; Xie, Z.; Yu, C.;* Hao, E.; Jiao, L.* Bright near-infrared a-tetraphenyletheneBODIPY nanoprobes with high aggregated state emission quantum yields in aqueous system for lipid droplet-specific imaging.?Mater. Chem. Front.?2021, 5, 3664.?http://pubs.rsc.org/en/content/articlelanding/2021/qm/d1qm00067e/unauth

20) Zhao, Y.; Zhao, Y.; Yu, C.;* Liu, S.; Liu, Y.; Hao, E.;* Jiao, L.; Xu, X.; Zhang, Z.;* Li, J.* A novel family of non-symmetric benzothieno[7,6-b]-fused BODIPYs: Synthesis, structures, photophysical properties and lipid droplet-specific imaging in vitro.?Dyes Pigments?2021, 196, 109748.?http://www.sciencedirect.com/science/article/pii/S0143720821006148.

21) Yu, C.; Fang, X.; Wu, Q.; Jiao, L.*; Sun, L.; Li, Z.; So, P.-K.; Wong, W.-Y.*; Hao, E.* A family of BODIPY-like, highly fluorescent and unsymmetrical Bis(BF2) pyrrolyl-acylhydrazone chromophore: BOAPY, Org. Lett. 2020, 22, 4588. DOI: 10.1021/acs.orglett.0c00940.

22) Wu, H.; Guo, X.; Yu, C.;* Wong, W.-Y.; Hao, E.; Jiao, L.* Highly photostable ketopyrrolyl-BODIPYs with red aggregation-induced emission characteristics for ultrafast wash-free mitochondria-targeted bioimaging. Dyes Pigments 2020, 176, 108209.?http://www.sciencedirect.com/science/article/pii/S0143720819329304.

23) Yu, Y.; Yu, C.;* Wu, ?Q.; Wang, ?H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF₂ complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533.?http://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00473d.

24) Yu, C.; Hao, E.;* Fang, X.; Wu, Q.; Wang, L.; Li, J.; Xu, L.; Jiao, L.;* Wong, W.-Y.* AIE-active difluoroboronated acyl hydrazone dyes ?(BOAHY) emitting across the entire visible region and their photo-switching properties. J. Mater. Chem. C 2019, 7, 3269.?http://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00316a.

25) Yu, C.;⁺ Huang, ?Z.;⁺ Gu, ?W.; Wu, Q.; Hao, E.;* Xiao, ?Y.;* Jiao, L.;* Wong, W.-Y.* A novel family of AIE-active Meso-2-ketopyrrolylBODIPYs: Bright solid-state red fluorescence, morphological properties, and application as viscosimeters in live cells. Mater. Chem. Front. 2019, 3, 1823.?http://pubs.rsc.org/en/content/articlehtml/2019/qm/c9qm00154a.

26) Yu, Y.; Yu, C.;* Wu, ?Q.; Wang, ?H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF₂ complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533. http://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc00473d

27)?Yu, C.; Huang, Z.; Wang, X.; Miao, W.; Wu, Q.; Wong, W.-Y.; Hao, E.;* Xiao, Y.;* Jiao L.* A family of highly fluorescent and unsymmetric Bis(BF₂) chromophore containing both pyrrole and N-heteroarene derivatives: BOPPY. Org. Lett.?2018, 20, 4462.?A Family of Highly Fluorescent and Unsymmetric Bis(BF2) Chromophore Containing Both Pyrrole and N-Heteroarene Derivatives: BOPPY | Organic Letters (acs.org)

28) Yu, C.;*?Li, T.; Wu, Q.; Hu, W.; Hao, E.; Jiao, L.* Synthesis structural and spectroscopic properties of quinoxaline-bridged bisBODIPYs. J. Porphyrins Phthalocyanines 2018, 22, 899.?http://www.worldscientific.com/doi/abs/10.1142/S1088424618500797

29) Lv, X.; Li, T.; Wu, Q.; Yu, C.;* Jiao, L.; Hao, E.* Polybrominated BOPHY dyes: synthesis, reactivity, and properties. J. Org. Chem. 2018, 83, 1134.?http://pubs.acs.org/doi/full/10.1021/acs.joc.7b02415

30) Yu, C.;* Miao, W.; Wang, J.; Hao, E.; Jiao, L.* PyrrolylBODIPYs: syntheses, properties, and application as environment-sensitive fluorescence probes. ACS Omega?2017, 2, 3551.?http://pubs.acs.org/doi/full/10.1021/acsomega.7b00444.

31) Cui, J.; Sheng, W.; Wu, Q.; Yu, C.;* Hao, E.; Bobadova-Parvanova, P.;* Storer, M.; Asiri, A. M.; Marwani, H. M.; Jiao, L.* Synthesis, structure, and properties of near-infrared [b]phenanthrene-fused BF₂ azadipyrromethenes. Chem. Asian J. 2017, 12, 2486. (Very Important Paper) http://onlinelibrary.wiley.com/doi/abs/10.1002/asia.201700876.

32) Yu, C.; Wu, Q.; Wang, J.; Wei, Y.; Hao, E.;* Jiao, L.* Red to near-infrared isoindole BODIPY fluorophores: synthesis, crystal structures, spectroscopic and electrochemical properties. J. Org. Chem. 2016, 81, 3761.?http://pubs.acs.org/doi/full/10.1021/acs.joc.6b00414.

33) Yu, C.; Wu, Q.; Wang, J.; Tian, Z.; Hao, E.;* Jiao, L.* Synthesis and photophysical properties of meso-aryloxy linked BODIPY monomers, dimers, and trimer. J. Porphyrins Phthalocyanines?2016, 20, 475.?http://www.worldscientific.com/doi/abs/10.1142/S1088424616500309.

34) Li, T.; Gu, W.; Yu, C.;* Lv, X.; Wang, H.; Hao, E.; Jiao, L.* Syntheses and photophysical properties of meso-phenylene bridged boron dipyrromethene monomers, dimers and trimer. Chin. J. Chem. 2016, 34, 989.?http://onlinelibrary.wiley.com/doi/abs/10.1002/cjoc.201600500.

35) Yu, C.; Jiao, L.;* Li, T.; Wu, Q.; Miao, W.; Wang, J.; Wei, Y.; Mu, X.; Hao, E.* Fusion and planarization of bisBODIPY: a new family of photostable near-infrared dyes. Chem. Commun. 2015, 51, 16852.?http://pubs.rsc.org/en/content/articlehtml/2015/cc/c5cc07304a.

36) Yu, C.; Hao, E.;* Li, T.; Wang, J.; Sheng, W.; Wei, Y.; Mu, X.; Jiao, L.* Dipyrrolylquinoxaline difluoroborates with intense red solid-state fluorescence. Dalton Trans. 2015, 44, 13897. (Hot Article)?http://pubs.rsc.org/en/content/articlehtml/2015/dt/c5dt02012c.

37) Yu, C.; Jiao, L.;* Zhang, P.; Feng, Z.; Cheng, C.; Wei, Y.; Mu, X. and Hao, E.* Highly fluorescent BF₂ complexes of hydrazine-Schiff base linked bispyrrole, Org. Lett. 2014, 16, 3048.?http://pubs.acs.org/doi/full/10.1021/ol501162f.

38) Yu, C.; Jiao, L.; Hao, E. Research progress of functional modification of borondipyrromethene (BODIPY) fluorescent dyes. China Science paper 2013, 8, 1291. (in Chinese)?http://www.paper.edu.cn/releasepaper/content/201301-1053/.

39) Yu, C.; Jiao, L.;* Tan, X.; Wang, J.; Xu, Y.; Wu, Y.; Yang, G.; Wang, Z.; Hao, E.* Straightforward acid-catalyzed synthesis of pyrrolyldipyrromethenes. Angew. Chem. Int. Ed. 2012, 51, 7688.?http://onlinelibrary.wiley.com/doi/full/10.1002/anie.201202850.

40) Yu, C.; Xu, Y.; Jiao, L.;* Zhou, J.; Wang, Z.; Hao, E.* Isoindole-BODIPY dyes as red to near-infrared fluorophores. Chem. Eur. J. 2012, 18, 6437.?http://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201200398.

41) Yu, C.; Jiao, L.;* Yin, H.; Zhou, Z.; Pang, W.; Wu, Y.; Wang, Z.; Yang, G.; Hao, E. α-/β-formylated borondipyrrin (BODIPY) dyes: regioselective syntheses and photophysical properties. Eur. J. Org. Chem. 2011, 28, 5460.?http://wiley.com/doi/full/10.1002/ejoc.201100736.

42) Jiao, L.;* Yu, C.; Wang, J.; Briggs, E. A.; Besley, A. L.; Robinson, D.; Ruedas-Rama, M. J.; Orte, A.; Crovetto, L.; Talavera, E. M.; Alvarez-Pez, J. M.; Van der Auweraer, M.; Boens, N. Unusual Spectroscopic and Photophysical Properties of meso-tert-ButylBODIPY in Comparison to Related Alkylated BODIPY Dyes. RSC Adv. 2015, 5, 89375.

43) Jiao, L.;* Yu, C.; Liu, M.; Wu, Y.; Cong, K.; Meng, T.; Wang, Y.; Hao, E. Synthesis and functionalization of asymmetrical benzo-fused BODIPY dyes. J. Org. Chem. 2010, 75, 6035.

44) Jiao, L.;* Yu, C.; Uppal, T.; Liu, M.; Li, Y.; Zhou, Y.; Hao, E.; Hu, X.; Vicente, M. G. H.* Long-wavelength red fluorescent dyes from 3,5-diiodo-BODIPYs. Org. Biomol. Chem. 2010, 8, 2517.

45) Jiao, L.;* Yu, C.; Li, J.; Wang, Z.; Wu, M.; Hao, E. β-FormylBODIPYs from Vilsmeyer-Haack Reaction. J. Org. Chem. 2009, 74, 7525.??

46) Li, Z.; Zhang, L.; Wu, Q.; Li, H.; Kang, Z.; Yu, C.; Hao, E.*; Jiao, L.* Boron-Templated Synthesis of B(III)-Submonoazaporphyrins: The Hybrids of B(III)-Subporphyrins and B(III)-Subporphyrazines. J. Am. Chem. Soc. 2022, 144, 6692. http://pubs.acs.org/doi/full/10.1021/jacs.2c01671.

4. 授权专利:

1) 孙营柱，钱婉萍，于长江，一种轴手性双硼荧光染料超分子体系及其制备方法, 中国发明专利，申请专利号：2024108552390.

2) 于长江，于婷婷，钱婉萍，郝二红，一种异吲哚亚胺吡啶肼双硼荧光染料及其制备方法和应用, 中国发明专利，申请专利号：2024107875741.

3) 于长江，程超，郝二红，双硼吡咯水杨酰腙荧光染料及其制备方法, 中国发明专利，申请专利号：2023108347283.

4) 于长江，程超，郝二红，苯并四硼吡咯水杨酰腙荧光染料及其制备方法, 中国发明专利，申请专利号：2023113135754.

5) 于长江，张子瑜，焦莉娟，郝二红，苯并二吡咯酮氟硼荧光染料及其制备方法, 中国发明专利，授权专利号：ZL201911274610.X.

6) 于长江，郝二红，焦莉娟，黄维扬，酰基吡啶肼双氟硼强荧光染料及其制备方法, 中国发明专利，授权专利号：ZL201811258192.0.

7) 于长江，郝二红，焦莉娟，黄维扬，meso-吡咯酮BODIPY染料粘度探针及其制备方法和应用, 中国发明专利，授权专利号：ZL201811258191.6.

8)?于长江，郝二红，焦莉娟，黄维扬，吡咯吡啶肼双氟硼荧光染料及其制备方法和应用，中国发明专利，授权专利号：ZL201810499299.8.

9) 黄维扬，于长江，双异吲哚铱(III)配合物及其制备方法，中国发明专利，授权专利号：ZL202010160840.X.

10) 焦莉娟，于长江，吴昊，郝二红，氟硼荧光探针在线粒体定位中的应用，中国发明专利，授权专利号：ZL202010039832.X.

11) 郝二红，于长江，焦莉娟，黄维扬，线性共轭异吲哚多吡咯色素及其制备方法，中国发明专利，授权专利号：CN201911275827.2.

12)?郝二红，于长江，张年荣，焦莉娟，一类吡咯腙肼双氟硼荧光染料及其制备方法，中国发明专利，授权专利号：CN201810499260.6.

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